Yes, this is possible when you have an account (free or paid).
Note. You also need this setting when you have dates in your Excel
1) Login at PDFen.com
2) Go to "My preferences"
3) Choose the deisred dateformat
After save you should see the right decimal sign after converting Excel (spreadsheet) files (xls, xlsx or ods)
Start converting your Excel files to PDF here: Excel to PDF at PDFen.com